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51.
通过多步法合成了离子型含双苯并三氮唑环的目标分子,4,4'-{苯-1,3-二基二[(1E)-3-羰基丙-1-烯-1,3-二基]}二[2-(2H-苯并三唑-2-基)苯醇酸]二钾。在室温条件下,目标分子在3.5%(质量)NaCl/DMSO(二甲基亚枫)混合溶液 (体积比:40/60) 中能够发生分子自组装产生纳-微米级的自聚集体。通过傅里叶变换红外光谱 (FT-IR)、拉曼光谱和X射线光电子能谱 (XPS) 的表征,证实了所形成的目标分子自聚集体能够对铜表面产生强烈的化学吸附作用,在铜表面形成自组装膜。利用电化学方法测定了目标分子自聚集体吸附在铜表面形成自组装膜后,在3.5%(质量)NaCl溶液中的缓蚀性能。结果表明目标分子自聚集体在NaCl溶液中能高效地抑制铜腐蚀。 相似文献
52.
为了解决脱硫石膏的大量堆存对环境造成的潜在危害,同时提高脱硫石膏的附加值,采用常压盐溶液水热法以电厂脱硫石膏为原料探究α-半水石膏的最佳合成工艺,重点研究了盐溶液种类及浓度对α-半水石膏的合成过程、合成产物组成及结构的影响。结果表明:在氯化钙、氯化镁盐溶液中,由于同离子效应和硫酸镁离子对的形成,导致半水石膏的形成过程受阻。较高浓度氯化钾和氯化钠盐溶液可使二水石膏发生转晶,其中氯化钾会致使半水石膏过度脱水生成无水钾石膏,氯化钠盐溶液可以使二水石膏转变为半水石膏并维持较长时间,通过比较得出最佳合成工艺为氯化钠溶液质量分数为15%、体系反应温度为95 ℃、固液质量比为1∶4、搅拌速率为150 r/min、合成时间为3 h,可以制得长径比约为5∶1的六方短柱状α-半水石膏。 相似文献
53.
本文主要对微弧氧化Mg-3Al-1Zn镁合金在空气和3.5 wt.%硫酸钠溶液两种环境下的应力腐蚀和腐蚀疲劳行为进行研究,并讨论其相互关系。微弧氧化处理后,Mg-3Al-1Zn镁合金的耐蚀性能得到明显改善。与Mg-3Al-1Zn镁合金基体相比,在空气中,微弧氧化后合金的应力腐蚀和腐蚀疲劳强度均下降了大约10 MPa。在3.5 wt.%硫酸钠溶液环境中,微弧氧化后合金的腐蚀疲劳性能仍然是恶化的,但是应力腐蚀强度却得到了显著改善,从58.24 MPa提高至202.08 MPa。这表明材料的力学性能(应力腐蚀和腐蚀疲劳)并不是与其腐蚀性能完全保持线性关系的。微弧氧化处理后镁合金在空气中的应力腐蚀断口为韧性断裂,在硫酸钠溶液环境中为解理断裂。而其腐蚀疲劳断口不论是在空气中还是在腐蚀环境中均为解理断裂。这主要是由于腐蚀环境和变换循环载荷的影响,两者共同作用将会加速裂纹扩展。这表明,周围环境和加载类型对材料断裂机理有重要影响。 相似文献
54.
在近α型TG6钛合金两相区淬火过程中,对初生α相αP周围形成的块状组织αm进行表征研究,块状组织αm与αP存在明显的界面,合金元素Al、Sn和Zr浓度介于αP和β基体之间,EBSD分析结果表明αm取向与αP保持一致。在冷却过程中,αP周围β基体中合金元素扩散受到限制,进而在局部过渡成分区域通过扩散转变形成αm组织。当固溶温度从1040℃提高至1060℃,同时保温时间从30 min减少为5 min,溶质元素扩散受限,αm体积分数从5.2%提升至30.7%。 相似文献
55.
为了探究带有方形肋及双倾斜肋片细通道的流动换热及熵产特性,设计了2种带有方形肋及双倾斜肋片的组合细通道(MCDS-L, MCDS-R),然后采用数值模拟的方法分析其流动特性、传热特性和熵产特性,并将其分析结果同2种方形肋细通道(MCS-L, MCS-R)和一种双倾斜肋片细通道(MCD)进行对比。结果表明,在所研究的雷诺数范围内,组合通道的摩擦阻力系数基本一致且均高于其他3组通道(MCS-L, MCS-R, MCD) 。此外,组合通道的努塞尔数均高于其他3组通道,而熵产增大数均低于其他3组通道。其中,MCDS-L通道的努塞尔数最大,熵产增大数最低。表明MCDS-L通道的换热效果最佳,能量的综合利用程度最高。研究成果为微细通道热沉的设计提供参考。 相似文献
56.
Thermodynamically stable (Hf1–xTax)C (x?=?0.1–0.3) compositions were selected by First Principle Calculation and synthesized in nanopowders via high-energy ball milling and carbothermal reduction of commercial oxides at 1450?°C. The formation of a solid solution during powder synthesis was investigated. The solid solution carbide powders were sintered at 1900?°C by spark plasma sintering without a sintering aid. As a result, the (Hf1–xTax)C solid solution carbides exhibited high densities, excellent hardness and fracture toughness (ρ: 98.7–100.0%, HVN: 19.69–19.98?GPa, KIC: 5.09–5.15?MPa?m1/2) compared with previously reported HfC and HfC–TaC solid solution carbides. 相似文献
57.
Imad Hussain S.N. Khan Eun Ji Kim So Eun Jeon Bon Heun Koo 《Ceramics International》2018,44(3):2892-2899
A systematic study focusing on the effect of Niobium (Nb) doping on the structural, magnetic and magnetocaloric properties of Ba2FeMoO6 samples is presented here. The samples of interest Ba2FeMo1?xNbxO6 (0 ≤ x ≤ 0.4) were prepared using the solid state reaction method and were confirmed to possess a cubic structure with Fm-3m space group using the X-ray diffraction analysis and Rietveld refinement. A second order of ferromagnetic phase transition was recorded in both the pure as well as the Nb doped samples using the temperature dependent magnetization and Arrott plots analysis. The pristine Ba2FeMoO6 (BFMO) sample indicated a spontaneous magnetization (34.6 emu/g at 100 K) with a relatively sharp magnetic transition at the Curie temperature (TC) of 315 K as compared to the doped samples. A magnetic entropy change of 0.93 Jkg?1K?1 at an applied magnetic field of 2.5 T was measured for the pure BFMO sample. The doped BFMO samples with Mo partially substituted by Nb however, were observed to effectively modify the TC accompanied by a decrease in magnetization. The results investigated in this work suggest that the magnetic and magnetocaloric properties of the BFMO can be tailored by controlled Nb doping which is of significant importance in order to realize the numerous potential applications of the material in the magnetic refrigeration technology. 相似文献
58.
Li Lei Limin Li Shasha Wang Gaoyang Zhao Yoshifumi Oshima Yang Ren Lei Zhao Lihua Jin Yao Wang Chengshan Li Pingxiang Zhang 《Journal of the European Ceramic Society》2018,38(14):4694-4700
Highly (100)-oriented Ce1-x(Y0.2Zr0.8)xOδ (CYZO) films were prepared on biaxially textured NiW substrates by a chemical solution deposition approach using metal inorganic salts as starting materials. It has been found that both the preferential orientation and surface roughness of CYZO films decrease gradually with increasing of the doping percentage of Y3+ and Zr4+ ions. The epitaxial growth relationship of (220)CYZO//(200)NiW and [00?l]CYZO//[001]NiW was demonstrated by XRD texture measurement as well as atomic resolution STEM observation. XRD, Raman and XPS spectra results indicate that Y3+ and Zr4+ ions were indeed introduced into CeO2 lattice to substitute Ce4+ ions and form cubic fluorite CYZO solid solution. Moreover, CeO2 buffer layer can be endowed a strong enough capability to prevent element diffusion through co-doping of yttrium and zirconium, provided that an optimal doping ratio of them is adopted. This will provide a new approach to fabricating strong-barrier single buffer layer for coated conductor. 相似文献
59.
J.P. Ramos T. Stora A.M.R. Senos P. Bowen 《Journal of the European Ceramic Society》2018,38(15):4882-4891
In the ISOL (Isotope Separator OnLine) method a target at high temperatures (up to 2300?°C), is bombarded with high energy protons in order to produce isotopes through nuclear reactions which are simultaneously extracted from the target, ionized and delivered to physics experiments. Due to the enhanced isotope release properties of nanosized porous materials, titanium carbide-carbon porous nanocomposites have been developed at CERN and tested up to 1500?°C. In the interest of the ISOL application, in this study we extended the range of temperatures up to 1800?°C, to test the sintering hindering capabilities of different carbon allotropes. Carbon black was the most effective with the smallest TiC crystallite size: <80?nm at 1800?°C. Additionally, using thermodynamic modelling, ex-situ X-ray powder diffraction and in-situ gas phase analysis, we show that there are interesting additional phase and lattice parameter changes due to the ZrO2 impurities from the attrition milling. 相似文献
60.
J.C. Fariñas R. Moreno A. Pérez M.A. García M. García-Hernández M.D. Salvador A. Borrell 《Journal of the European Ceramic Society》2018,38(5):2360-2368
A simple, soft, and fast microwave-assisted hydrothermal method was used for the preparation of nanocrystalline cobalt ferrite powders from commercially-available Fe(NO3)3?9H2O, Co(NO3)2?6H2O, ammonium hydroxide, and tetrapropylammonium hydroxide (TPAH). The synthesis was conducted in a sealed-vessel microwave reactor specifically designed for synthetic applications, and the resulting products were characterized by XRD, FE-SEM, TEM, and HR-TEM. After a systematic study of the influence of the microwave variables (temperature, reaction time and nature of the bases), highly crystalline CoFe2O4 nanoparticles with a high uniformity in morphology and size, were directly obtained by heating at 130?°C for 20?min using the base TPAH. Dense ceramics of cobalt ferrite were prepared by non-conventional, microwave sintering of synthesized nanopowders at temperatures of 850–900?°C. The magnetic properties of both the nanopowders and the sintered specimens were determined in order to establish their feasibility as a permanent magnet. 相似文献